What is ACTIVE CARBON?

September 27, 2024

Active Carbon (also called activated carbon or activated charcoal) is a highly porous form of carbon with a large surface area, used for adsorption, purification, and filtration purposes. It's “activated” through a process of physical or chemical treatment, which increases its adsorption capacity. This property makes it extremely useful in many industries, particularly in the chemical industry.



Properties and Characteristics of Active Carbon:


  • High surface area: The porous structure provides a vast surface area (up to 1,500 m²/g) for adsorption.
  • Adsorptive capabilities: It can adsorb a wide variety of compounds, including gases, liquids, and organic molecules.
  • Physical and chemical stability: It remains stable in both acidic and basic environments.
  • Reusability: Can be regenerated by heating or chemical processes.



Applications of Active Carbon in the Chemical Industry:


  1.   Water treatment: Used in purification to remove contaminants such as chlorine, organic compounds, and toxins from water.

    2.    Gas purification: Removes impurities such as volatile organic compounds (VOCs), and toxic gases (like sulfur compounds) from industrial exhausts.

    3.    Catalysis: Acts as a support material for catalysts in chemical reactions.

    4.    Solvent recovery: Adsorbs and recovers organic solvents in industries like paint and coating manufacturing.

    5.    Deodorization: Used to eliminate odors by adsorbing unwanted gases and vapors.

    6.    Pharmaceutical applications: Used in medical settings to treat poisonings and overdoses (by adsorbing toxins in the gastrointestinal tract).

    7.    Food and beverage industry: For purifying ingredients (e.g., removal of color and impurities from sugar solutions).





Types of Activated Carbon (Based on Raw Materials):


  1.        Wood-based Activated Carbon:
        •        Derived from wood sources, often used in air purification and water treatment.
        •        Has a high adsorption capacity for larger molecules (macropores).
 

  2.        Coconut Shell-based Activated Carbon:
        •        Sourced from coconut shells, known for its high hardness and ability to adsorb smaller molecules.
        •        Commonly used in gas phase applications and water treatment (due to its microporosity).
 

  3.        Coal-based Activated Carbon:
        •        Made from anthracite or bituminous coal.
        •        Suitable for water purification, air filtration, and gas-phase adsorption.
       

  4.        Peat-based Activated Carbon:
        •        Derived from decomposed organic materials like peat.
        •        Typically used for water filtration due to its lower density and higher adsorption of organic compounds.
         

  5.        Polymer or synthetic-based Activated Carbon:
        •        Produced from synthetic polymers.
        •        Used in specialized applications like catalysis, where controlled pore structure is critical.


Biggest Producers of Activated Carbon:


The production of activated carbon is concentrated in regions with abundant natural resources like coconut shells, coal, and wood. Some of the largest producers include:

1.       
China:
        •        The world’s largest producer and exporter of activated carbon, especially coal-based and wood-based types.
        •        Has a significant capacity for producing various grades of activated carbon for industrial, water treatment, and air purification markets.
   

2.        India:
        •        A leading producer of coconut shell-based activated carbon.
        •        The country has a large export market, particularly in Southeast Asia and Europe, due to its high-quality activated carbon production.
       

3.        USA:
        •        A major producer of coal-based activated carbon, especially for domestic applications like air filtration and water treatment.
        •        The US also imports a significant amount of activated carbon from other countries.
       

4.        Indonesia:
        •        Known for producing coconut shell-based activated carbon due to its abundant coconut resources.
        •        Has a strong export market, supplying activated carbon to various global industries.
       

5.        Philippines:
        •        Another significant producer of coconut shell-based activated carbon, primarily for water filtration and air purification applications.


These countries dominate the global activated carbon market, driven by demand from industries such as environmental protection, water treatment, pharmaceuticals, and chemical processing.


Decachem Blog Team.

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In industrial settings, equipment and piping systems are constantly exposed to water, steam and a variety of process chemicals. Over time, this exposure leads to the buildup of mineral scale - primarily composed of calcium, magnesium and iron compounds - as well as other types of residues and contaminants. Left untreated, these deposits can reduce operational efficiency, cause blockages, damage machinery, and ultimately increase maintenance costs and downtime. This is where industrial descaling and cleaning become essential parts of routine maintenance. Descaling refers specifically to the removal of mineral scale, while cleaning more broadly covers the elimination of oils, rust, chemical residues and other contaminants. To achieve effective results, acids are commonly used due to their ability to dissolve or react with the unwanted deposits. Various acids like hydrochloric, sulfuric, citric and phosphoric acid are employed depending on the material compatibility, type of scale and environmental considerations. Among these, high-purity phosphoric acid stands out as an optimal choice for many industries. Its unique chemical properties make it not only effective at breaking down scale but also safer, less corrosive and more versatile than many alternatives. In the sections that follow, we'll explore why high-purity phosphoric acid is a preferred solution for industrial maintenance applications. What is High-Purity Phosphoric Acid? Chemical Composition and Manufacturing Process Phosphoric acid (H₃PO₄) is a mineral acid widely used in industrial, food and pharmaceutical applications. While technical-grade phosphoric acid contains a mixture of impurities and by-products from the manufacturing process, high-purity phosphoric acid is carefully refined to meet stringent quality and purity specifications. The key difference lies in the degree of purification . High-purity grades are produced through advanced filtration, extraction and distillation processes that remove heavy metals, fluorides, chlorides and other trace contaminants. These refined products meet internationally recognized standards, such as FCC (Food Chemicals Codex), ACS (American Chemical Society), or E339 for food additives . Typically, high-purity phosphoric acid contains 85% concentration with minimal levels of impurities , often below 1 ppm for critical elements. This high level of consistency and cleanliness ensures the acid is suitable for applications requiring maximum performance and minimal contamination risk — such as electronics manufacturing, pharmaceuticals, and high-end cleaning solutions. Why Purity Matters in Industrial Applications In industrial maintenance, the quality of cleaning agents directly affects both the effectiveness of the process and the longevity of equipment . Using lower-grade acids may introduce unwanted contaminants , including metal ions or organic residues, which can corrode metal surfaces, leave residues, or react unpredictably with other materials. In contrast, high-purity phosphoric acid reduces the risk of contamination , ensuring safer application and more predictable results. It is also less aggressive toward sensitive surfaces, offering enhanced material compatibility and reduced corrosion , especially in stainless steel systems. The result is greater efficiency, longer equipment life, and better compliance with regulatory and quality standards across industries. Key Industrial Applications of Phosphoric Acid in Maintenance Scale Removal in Boilers, Heat Exchangers, and Pipelines One of the most common maintenance challenges in industrial systems is the buildup of scale - solid mineral deposits primarily composed of calcium carbonate, magnesium salts and iron oxides. These deposits restrict flow, reduce heat transfer efficiency, and can lead to costly system failures. Phosphoric acid is highly effective at dissolving these mineral scales due to its ability to react with alkaline compounds, converting them into water-soluble salts that can be easily flushed out of the system. High-purity phosphoric acid is especially beneficial in this context because it performs efficiently without introducing additional contaminants that could damage sensitive components or leave residual deposits. It is commonly used in boiler descaling, heat exchanger maintenance, and pipeline flushing in a range of industries, from power generation to chemical processing. Rust and Corrosion Control Phosphoric acid also plays a dual role in rust removal and corrosion prevention. When applied to steel and other ferrous metals, it reacts with iron oxides (rust) to form iron phosphate, a stable compound that can act as a protective layer. This process not only removes rust but also passivates the metal surface, slowing future corrosion. Unlike more aggressive acids, high-purity phosphoric acid is gentler on the base material, making it an ideal choice for surface preparation before painting, coating or welding. Its controlled action ensures effective cleaning without over-etching or weakening the structure of the metal. Cleaning of Food-Grade and Pharmaceutical Equipment In industries with strict hygiene and regulatory requirements, such as food processing and pharmaceutical production, the cleaning process must be both effective and safe. High-purity phosphoric acid meets these demands thanks to its non-toxic nature and compliance with food-grade standards like FCC and E339. It is widely used to clean stainless steel tanks, pipes and mixing vessels, removing residues, biofilms, and scaling without compromising product safety. Because it leaves no harmful residues and does not introduce foreign contaminants, it supports both GMP compliance and product quality assurance, making it a trusted solution in sanitary maintenance protocols. Benefits of Using High-Purity Phosphoric Acid Over Other Cleaning Agents Compared to Hydrochloric Acid Hydrochloric acid is a strong and commonly used descaling agent, but it comes with several drawbacks that limit its suitability for sensitive industrial applications. One major concern is its high corrosiveness , especially toward metals like stainless steel and aluminum. It can rapidly degrade equipment surfaces, leading to costly repairs or premature replacement. In contrast, high-purity phosphoric acid is much gentler on metal surfaces , making it ideal for cleaning without compromising the integrity of machinery. It also produces far fewer harmful fumes , improving worker safety and reducing the need for intensive ventilation systems. For facilities seeking a balance between cleaning power and material compatibility, phosphoric acid provides a more controlled and less aggressive alternative. Compared to Citric and Sulfamic Acids Citric acid and sulfamic acid are often chosen for their lower toxicity and eco-friendliness, but they also come with limitations. Citric acid , while safe, is typically less effective at dissolving stubborn mineral scale, especially in high-deposit environments. It can also leave sticky residues that require additional rinsing. Sulfamic acid offers better performance, but its efficiency still falls short in comparison to phosphoric acid for certain applications. High-purity phosphoric acid strikes a strong balance between cleaning strength and safety . It effectively dissolves scale and rust without excessive foaming or residue issues, offering an excellent cost-performance ratio in both industrial and hygienic environments. Longevity and Preventive Maintenance Effects One of the often-overlooked advantages of high-purity phosphoric acid is its contribution to preventive maintenance . Its ability to clean thoroughly without damaging surfaces means that equipment stays cleaner for longer periods , and the frequency of cleaning cycles is reduced . Additionally, its passivating effects help form protective layers on metal surfaces, leading to lower wear and tear over time. This contributes to extended equipment life, fewer unplanned shutdowns, and overall improved operational reliability - key goals for any maintenance strategy.